Preparation of Nitrogen Monoxide
and
Study of Its Chemical Properties
(microscale experiment)
Sodium nitrite 亞硝酸鈉粉末 |
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Acidified iron(II) sulphate solution 酸化硫酸鐵(II)溶液 |
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1 M sodium hydroxide solution 1 M 氫氧化鈉溶液 |
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Acidified potassium permanganate solution 酸化高錳酸鉀溶液 |
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Bromine water 溴水 |
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Add 100 cm3 of 1 M NaOH solution and 250 cm3 of deionised water into two different 250 cm3 beakers respectively. 在兩個250 cm3的燒杯中分別加入100 cm3的 1 M 氫氧化鈉溶液和250 cm3的去離子水。
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Check whether the pluger moves smoothly in the syringe. Lubricate the plunger if necessary. 檢查柱塞能否在針筒內順暢地拉推。如有需要, 在柱塞表面塗上潤滑劑。 |
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Weigh about 0.25 g of NaNO2 and transfer it into a vial cap. 用電子天平稱量0.25 g的亞硝酸鈉粉末,然後將 其加至一個塑製瓶蓋裡。 |
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Make sure that the NaNO2 solid is evenly placed in the cap. 請確保亞硝酸鈉粉末均勻地分佈在蓋裡。 |
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Cap the tip. Fill the syringe with water. 蓋上針筒口。加去離子水進到直立的針筒中。 |
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Put the vial cap on the water surface. 把預備的塑製瓶蓋放在針筒裡水的表面。 |
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Uncap the syringe to allow water to drain out from the syringe. 打開針筒口讓水從針筒中流出來。 |
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Insert the plunger, and draw about 4 cm3 of acidified FeSO4(aq) into the syringe. 插入柱塞到針筒內, 把大約4 cm3的酸化 硫酸鐵(II)溶液抽進針筒內。 |
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Cap the syringe immediately and shake the syringe gently to mix the NaNO2 solid and acidified FeSO4(aq). 即時地蓋上針筒口。 輕輕搖動針筒讓針筒內 的亞硝酸鈉粉末與酸化硫酸鐵(II)溶液混合。
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Discharge the solution inside the syringe into 1 M NaOH solution. 讓針筒內的溶液流出到1M 氫氧化鈉溶液中。 |
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Draw 10 cm3 of deionised water intno the syringe. Shake the syringe to wash the gas inside the syringe. 把大約10 cm3去離子水抽進到針筒內,以清洗 收集回來的一氧化氮。 |
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Discharge the water from the syringe into 1 M NaOH solution. Repeat the steps of drawing the water and discharging water for 2 to 3 times. 讓針筒內的溶液流出到1M 氫氧化鈉溶液中。 重覆清洗步驟兩至三次。 |
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Add 5 cm3 of acidified KMnO4(aq), Br2(aq), and acidified FeSO4(aq) to these test tubes respectively. 分別在每個試管中加入5 cm3的酸化高錳酸鉀 溶液、溴水和酸化硫酸鐵(II)溶液。 |
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Inject a small amount of nitrogen monoxide from the syringe into each of the solutions. 用針筒將少量的一氧化氮各自加入盛有不同溶 液的試管內。 |
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Record the changes observed. 記錄可觀察的變化。 |
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With NO(g) left in the syringe, suck in small amount of air into the syringe by pulling the plunger slowly. Record the observation. 將部份柱塞慢慢地拉出,令少量的空氣能夠進 入針筒內,以研究一氧化氮與氧氣的反應。記 錄可觀察的變化。 |